Character | How to unlock |
| Cai Wenji | Beat Chapter 2 - “Battle of Anegawa” |
| Cao Cao | Beat Chapter 3 - “Battle of Fancheng” |
| Cao Pi | Beat Chapter 3 - “Battle of Hu Lao Gate” |
| Cao Ren | Beat Chapter 2 - “Battle of Mount Ding Jun” |
| Dian Wei | Beat Chapter 3 - “Battle of Nagasaka Post-modification” |
| Guo Jia | Beat Chapter 3 - “Battle of Fancheng Post-modification” |
| Jia Xu | Beat Chapter 1 - “Battle of Dong Kou” |
| Pang De | Beat Chapter 1 - “Battle of Yi Ling" |
| Wang Yi | Beat Chapter 4 - “Battle of Nagashino” |
| Xiahou Dun | Beat Chapter 3 - “Battle of Fancheng” |
| Xiahou Yuan | Beat Chapter 1 - “Battle of Nan-Jun” |
| Xu Chu | Beat Chapter 3 - “Battle of Tong Gate” |
| Xu Huang | Beat Chapter 1 - “Battle of Dong Kou” |
| Zhang He | Beat Chapter 2 - “Battle of Xuchang” |
| Zhang Liao | Beat Chapter 1 - “Battle of Ueda Castle” |
| Zhen Ji | Beat Chapter 3 - “Battle of Hu Lao Gate” |
